14132-13-9Relevant academic research and scientific papers
Reaction of singlet oxygen with thioanisole in ionic liquids: A solvent induced mechanistic dichotomy
Baciocchi, Enrico,Chiappe, Cinzia,Del Giacco, Tiziana,Fasciani, Chiara,Lanzalunga, Osvaldo,Lapi, Andrea,Melai, Bernardo
, p. 1413 - 1416 (2009)
A study of the reaction of thioanisole with singlet oxygen in pyrrolidinium-and imidazolium-based ionic liquids has been carried out. In these solvents, thioanisole shows a strongly enhanced reactivity with respect to molecular aprotic solvents, probably
A novel synthesis of aryl methyl sulfones and β-hydroxysulfones from sodium sulfinates and di-tert-butyl peroxide in H2O medium
Lai, Junyi,Yuan, Gaoqing
, p. 524 - 527 (2018/01/10)
A novel and convenient synthetic route for aryl methyl sulfones and β-hydroxysulfones was developed via the radical reaction between sodium sulfinates and di-tert-butyl peroxide (DTBP). Without any catalysts and additives, the synthetic process could be smoothly carried out to afford the target products in good to excellent yields in H2O medium, demonstrating its promising application. In the present system, H2O could act not only as a green solvent but also as a reactant.
Evidence for the involvement of a sulfurane intermediate in the oxidation of simple sulfides by methyl(trifluoromethyl)dioxirane
Asensio, Gregorio,Mello, Rossella,Gonzalez-Nunez, Maria Elena
, p. 2299 - 2302 (2007/10/03)
Methyl(trifluoromethyl)dioxirane reacts with sulfides to give preferentially sulfones, even in the presence of competing sulfoxides. The sulfoxide yield increases at the expense of the sulfone when 2,2,2-trifluoroethanol is used as co-solvent. The reactio
