141327-85-7

Basic information

• Product Name: Benzenemethanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,5-dimethoxy-
• CAS NO: 141327-85-7
• Molecular Formula: C15H26O4Si
• Molecular Weight: 298.455
• Mol File: 141327-85-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,5-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,5-dimethoxy-(141327-85-7)
• EPA Substance Registry System: Benzenemethanol, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3,5-dimethoxy-(141327-85-7)

Safety Data

• Hazardous Substances Data: 141327-85-7(Hazardous Substances Data)

Upstream product

• 106852-80-6 4-(t-butyldimethylsilyloxy)-3,5-dimethoxybenzaldehyde 
• 134-96-3 syringic aldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 158555-91-0 1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethoxy-4-<4-butyl>benzene 
• 158555-50-1 1-<(tert-Butyldimethylsilyl)oxy>-2,6-dimethoxy-4-<4-(indol-3-yl)butyl>benzene 
• 158555-61-4 2,6-Dimethoxy-4-<4-butylidene>-2,5-cyclohexadien-1-one 
• 158555-52-3 2,6-Dimethoxy-4-<4-butyl>phenol 
• 158555-66-9 (+/-)-2-<(3,5-Dimethoxy-4-oxo)-2,5-cyclohexadienylidene>spiroindole> 
• 158555-51-2 2,6-Dimethoxy-4-<4-(indol-3-yl)butyl>phenol 
• 158555-49-8 (4-Bromomethyl-2,6-dimethoxy-phenoxy)-tert-butyl-dimethyl-silane 

Relevant articles and documents

Highly sulphated cellulose: a versatile, reusable and selective desilylating agent for deprotection of alcoholic TBDMS ethers

A mild, efficient and rapid protocol was developed for the deprotection of alcoholic TBDMS ethers using a recyclable, eco-friendly highly sulphated cellulose sulphate acid catalyst in methanol. This acid catalyst selectively cleaves alcoholic TBDMS ethers in bis-TBDMS ethers containing both alcoholic and phenolic TBDMS ether moieties.

Formation of Carbon-Carbon Bonds via Quinone Methide-Initiated Cyclization Reactions

p-Quinone methides were found to be excellent electrophilic cyclization initiators for the formation of six-membered rings.Cyclizations to form five- and seven-membered rings were also studied.Oxidation of 2,6-disubstituted phenols with Ag2O afforded the