141344-99-2Relevant articles and documents
Reactivity of Malonyl Radicals. Synthesis of Substituted Dihydronaphthalenes by Mn(III) Oxidation of Diethyl α-Benzylmalonate in the Presence of Alkynes
Santi, Roberto,Bergamini, Fabrizio,Citterio, Attilio,Sebastiano, Roberto,Nicolini, Marco
, p. 4250 - 4255 (2007/10/02)
Oxidation of diethyl α-benzylmalonate (1) by Mn(III) acetate in acetic acid at 70 deg C in the presence of alkynes 2a-j leads to dihydronaphthalene derivatives 3a-j in moderate to good yields.A homolytic mechanism, involving oxidation of 1 to the correspo