141353-29-9

Upstream product

• 460313-68-2 3-(2-chloroacetyl)oxazolidin-2-one 
• 603-35-0 triphenylphosphine 
• 141353-28-8 3-bromoacetyl-1,3-oxazolidin-2-one 

Downstream Products

• 867039-48-3 4-methyl-N-(3-methyl-but-2-enyl)-N-[5-oxo-5-(2-oxo-oxazolidin-3-yl)-pent-3-enyl]-benzenesulfonamide 
• 460313-72-8 (3'R,4''S)-3-[3'-benzyloxyamino-3'-(2'',2''-dimethyl-1'',3''-dioxolan-4''-yl)propanoyl]oxazolidin-2-one 

Relevant academic research and scientific papers

Lewis acid-promoted synthesis and reactivity of β-O-benzylhydroxylamino imides derived from D-glyceraldehyde

This paper describes the synthesis and use β-hydroxylamino imides derived from D-glyceraldehyde possessing a number of reactive sites that operate synergistically or alternatively to bring about highly regio- and diastereoselective transformations to give an optically pure aziridine-2-imide, a dihydro pyrimidine-2,4-dione, or a lactone. Both the syntheses, via the diastereoselective 1,4-conjugate addition of O-benzyl hydroxylamine to α,β-unsaturated imides, and transformations can be simply tuned by choosing between different Lewis acids.

Asymmetric Diels-Alder reactions of N-allenoyloxazolidinones catalyzed by Cu(II)-bis(oxazoline) complexes

Catalytic asymmetric Diels-Alder reactions of N-allenoyloxazolidinones were investigated. Various chiral metal-bis(oxazoline) and metal-pyridinebis(oxazoline) complexes were screened. Cu(SbF6)2(H2O)2(t-BuBox) wa

Asymmetric Intramolecular Ene Reaction Catalyzed by a Chiral Titanium Reagent and Synthesis of (-)-ε-Cadinene

A highly diastereo- and enantio-selective intramolecular ene reaction was developed by employing a chiral titanium reagent generated in situ from TiCl2(OPri)2 and a tartrate-derived chiral 1,4-diol.This reaction afforded masked cyclohexanone an