170458-46-5Relevant academic research and scientific papers
Ni-Catalyzed Carboxylation of Aziridines en Route to β-Amino Acids
Davies, Jacob,Janssen-Müller, Daniel,Zimin, Dmitry P.,Day, Craig S.,Yanagi, Tomoyuki,Elfert, Jonas,Martin, Ruben
supporting information, p. 4949 - 4954 (2021/04/07)
A Ni-catalyzed reductive carboxylation of N-substituted aziridines with CO2 at atmospheric pressure is disclosed. The protocol is characterized by its mild conditions, experimental ease, and exquisite chemo- and regioselectivity pattern, thus unlocking a new catalytic blueprint to access β-amino acids, important building blocks with considerable potential as peptidomimetics.
27- To 39-membered pyridine macrocycles
Luening, Ulrich,Mak, Ellen,Zindler, Melanie,Hartkopf, Britta,Herges, Rainer
experimental part, p. 4932 - 4940 (2010/11/04)
A set of 27- to 39-membered pyridine macrocycles 2 and 3 has been synthesized by Williamson ether synthesis or ringclosing metathesis. The pyridines are 2,6-disubstituted to al-low endo interactions. In addition to the length, also the nature of the aliphatic chain was varied: saturated (2) and unsaturated (3).
Surface-initiated ring-opening metathesis polymerization (SI-ROMP): Synthesis and electropolymerization of terthiophene-functionalized olefin peripheral dendrons
Jiang, Guoqian,Ponnapati, Ramakrishna,Pernites, Roderick,Felipe, Mary Jane,Advincula, Rigoberto
experimental part, p. 10262 - 10274 (2011/08/04)
We report on the synthesis and electrodeposition of peripheral olefin dendrons with electropolymerizable focal point terthiophene units. These films were utilized for surface initiated ring-opening metathesis polymerization (SI-ROMP) of norbornene to form
