1414791-67-5

Basic information

• Product Name: [PdCl₂(N,N-di-metyl-2,11-diaza[3,3](2,6)pyridinophane)]
• Synonyms: [PdCl₂(N,N-di-metyl-2,11-diaza[3,3](2,6)pyridinophane)]
• CAS NO: 1414791-67-5
• Molecular Weight: 445.688
• Mol File: 1414791-67-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [PdCl₂(N,N-di-metyl-2,11-diaza[3,3](2,6)pyridinophane)](CAS DataBase Reference)
• NIST Chemistry Reference: [PdCl₂(N,N-di-metyl-2,11-diaza[3,3](2,6)pyridinophane)](1414791-67-5)
• EPA Substance Registry System: [PdCl₂(N,N-di-metyl-2,11-diaza[3,3](2,6)pyridinophane)](1414791-67-5)

Safety Data

• Hazardous Substances Data: 1414791-67-5(Hazardous Substances Data)

Upstream product

• 56-34-8 tetraethylammonium chloride 

Relevant articles and documents

Structural and reactivity comparison of analogous organometallic Pd(iii) and Pd(iv) complexes

The tetradentate ligands RN4 (RN4 = N,N′-di-alkyl-2,11-diaza[3,3](2,6)pyridinophane, R = Me or iPr) were found to stabilize cationic (RN4)PdMe2 and ( RN4)PdMeCl complexes in both PdIII and PdIV oxidation states. This allows for the first time a direct structural and reactivity comparison of the two Pd oxidation states in an identical ligand environment. The PdIII complexes exhibit a distorted octahedral geometry, as expected for a d7 metal center, and display unselective C-C and C-Cl bond formation reactivity. By contrast, the PdIV complexes have a pseudo-octahedral geometry and undergo selective non-radical C-C or C-Cl bond formation that is controlled by the ability of the complex to access a five-coordinate intermediate. The Royal Society of Chemistry 2012.