141483-98-9

Basic information

• Product Name: 3-Cyclohexen-1-ol, 4-methyl-, (R)-
• CAS NO: 141483-98-9
• Molecular Formula: C7H12O
• Molecular Weight: 112.172
• Mol File: 141483-98-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexen-1-ol, 4-methyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexen-1-ol, 4-methyl-, (R)-(141483-98-9)
• EPA Substance Registry System: 3-Cyclohexen-1-ol, 4-methyl-, (R)-(141483-98-9)

Safety Data

• Hazardous Substances Data: 141483-98-9(Hazardous Substances Data)

Upstream product

• 78-79-5 isoprene 
• 351184-36-6 (4R)-1-methyl-4-acetoxycyclohexane 1,2-oxide 
• 141483-97-8 (+)-(1R)-4-methyl-1-acetoxy-3-cyclohexene 

Downstream Products

• 93915-81-2 (-)-(1S)-4-methyl-3-cyclohexen-1-ol 
• 141484-09-5 (+)-(1R)-4-methyl-3-cyclohexenamine 
• 141484-01-7 (-)-(1S)-4-methyl-3-cyclohexenamine 
• 141484-10-8 (-)-(1R)-N,4-dimethyl-3-cyclohexenamine 
• 141484-02-8 (-)-(1S)-N,4-dimethyl-3-cyclohexenamine 
• 141484-08-4 (1R)-1-azido-4-methyl-3-cyclohexene 
• 141484-00-6 (1S)-1-azido-4-methyl-3-cyclohexene 
• 141484-06-2 (-)-(1S)-4-methyl-1-acetoxy-3-cyclohexene 
• 141484-16-4 (+)-(1R)-1-methyl (4-methyl-3-cyclohexenyl)carbamate 
• 141484-14-2 (-)-(1S)-1-methyl (4-methyl-3-cyclohexenyl)carbamate 
• 141484-13-1 (+)-(1R)-N,4-dimethyl-N-(4-methyl-3-pentenyl)-3-cyclohexenamine 
• 141484-05-1 (-)-(1S)-N,4-dimethyl-N-(4-methyl-3-pentenyl)-3-cyclohexenamine 
• 141484-12-0 (+)-(1R)-N,4-dimethyl-N-(4-methyl-3-cyclohexenyl)-3-pentenamide 
• 141484-04-0 (-)-(1S)-N,4-dimethyl-N-(4-methyl-3-cyclohexenyl)-3-pentenamide 

Relevant articles and documents

Stereoselective [4+2]-Cycloaddition with Chiral Alkenylboranes

A method for the stereoselective [4+2]-cycloaddition of alkenylboranes and dienes is presented. This transformation was accomplished through the introduction of a new strategy that involves the use of chiral N-protonated alkenyl oxazaborolidines as dieneophiles. The reaction leads to the formation of products that can be readily derivatized to more complex structural motifs through stereospecific transformations of the C?B bond such as oxidation and homologation. Detailed computation evaluation of the reaction has uncovered a surprising role of the counterion on stereoselectivity.