141523-84-4Relevant academic research and scientific papers
Stereocontrolled 1,4-Asymmetric Reduction of Cyclic Hemiketals. Synthesis of Both anti- and syn-1,4-Diols, and Their Transformations into trans- and cis-2,5-Disubstituted Tetrahydrofurans
Chikashita, Hidenori,Fukushima, Takashi,Uemura, Hiromitsu,Itoh, Kazuyoshi
, p. 599 - 602 (1992)
Reduction of dithioacetal-functionalized cyclic hemiketals with LiAlH4 in THF and NaBH4 in ethanol gave the corresponding anti- and syn-1,4-diols with excellent stereoselectivity, respectively.The anti- and syn-1,4-diols were easily transformed into trans
