Chemistry Letters p. 599 - 602 (1992)
Update date:2022-08-03
Topics: Synthesis Stereocontrolled Cis-2,5-Disubstituted Tetrahydrofurans 1,4-Asymmetric Reduction Cyclic Hemiketals anti-1,4-Diols syn-1,4-Diols trans-2,5-Disubstituted Tetrahydrofurans
Chikashita, Hidenori
Fukushima, Takashi
Uemura, Hiromitsu
Itoh, Kazuyoshi
Reduction of dithioacetal-functionalized cyclic hemiketals with LiAlH4 in THF and NaBH4 in ethanol gave the corresponding anti- and syn-1,4-diols with excellent stereoselectivity, respectively.The anti- and syn-1,4-diols were easily transformed into trans
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