1415262-29-1Relevant articles and documents
The cyclisation of 2'-aminochalcones using silica-supported Yb(OTf)3 under solvent-free conditions
Li, Jianjun,Jin, Linyong,Yu, Chuanming,Su, Weike
, p. 170 - 173 (2009)
Silica-supported Yb(OTf)3 is utilised as a catalyst for the synthesis of 2-substituted dihydroquinolinones from 2'-amino chalcones in good yields. The catalyst is easily prepared and is active under solvent-free conditions and environmentally friendly con
Organometallic titanocene complex as highly efficient bifunctional catalyst for intramolecular Mannich reaction
Wang, Yunyun,Jian, Yajun,Wu, Ya,Sun, Huaming,Zhang, Guofang,Zhang, Weiqiang,Gao, Ziwei
, (2019/05/07)
Bifunctional catalysts bearing two catalytic sites, Lewis acidic organometallic titanocene and Br?nsted acidic COOH, have been assembled in situ from Cp2TiCl2 with carboxylic acid ligands, showing high catalytic activity over an intramolecular Mannich reaction towards synthesis of 2-aryl-2,3-dihydroquinolin-4(1H)-ones. The determination of the bifunctional catalyst Cp2Ti(C8H4NO6)2 was elucidated by single X-ray HR-MS and investigation of catalytic behavior. In particular, masking the Br?nsted acidic COOH catalytic site with dormant COOMe lowered the reaction yield greatly, indicating that two catalytic sites work together to maintain high catalytic efficiency.
Titanocene complex with oxygen-containing carboxylic acid as ligand as well as preparation method and application of titanocene complex
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Paragraph 0039; 0040; 0042, (2018/11/03)
The invention discloses a titanocene complex with oxygen-containing carboxylic acid as well as a preparation method and an application of the titanocene complex. The structural formula of the complexis shown in the description. The titanocene complex is p