1415265-13-2Relevant academic research and scientific papers
Synthesis of substituted phenols via 1,1-dichloro-2-nitroethene promoted condensation of carbonyl compounds with DMF
Wang, Fukai,Wu, Wei,Xu, Xiaoyong,Shao, Xusheng,Li, Zhong
supporting information, p. 2506 - 2510 (2018/05/30)
A novel and efficient metal-free synthesis of phenolic compounds was developed via coupling cyclization of DMF as a carbon source with active methylene compounds such as 1,3-dicarbonyl compounds with the assistance of 1,1-dichloro-2-nitroethene. The method we used was different from other traditional phenol functionalization methods. In the reaction, the 1,1-dichloro-2-nitroethene as a promoter which unlike our previous research on 1,1-dichloro-2-nitroethene. The method allows the convenient construction of phenolic compounds under mild reaction conditions and moderate yields.
Palladium-catalyzed formation of phenolic compounds by reaction of carbonyl compounds with carbon dioxide
Gao, Qi,Tan, Xian-Chun,Pan, Ying-Ming,Wang, Heng-Shan,Liang, Ying
supporting information, p. 12080 - 12081 (2013/01/16)
The use of carbon dioxide as a renewable and environmentally friendly source of carbon is highly attractive. A novel and efficient protocol for the synthesis of phenolic compounds from carbonyl compounds and carbon dioxide in the presence of a catalytic amount of Pd(OAc)2 has been developed. This reaction is appealing for industries and is a tool for the sequestration of carbon dioxide.
