1415357-10-6Relevant articles and documents
Metallic chalcogenolates mediated modular Michael-aldol cascade reaction: An easy route to multi-functionalized chalcogenides and Morita-Baylis-Hillman adducts
Sousa, Bruno A.,Comasseto, Joao V.,Dos Santos, Alcindo A.,Keppler, Arthur F.,Gariani, Rogerio A.
, p. 10406 - 10413,8 (2012)
Chalcogenolate mediated Michael-aldol cascade reactions consists of a very efficient route to multi-functionalized γ-hydroxichalcogenides. Although, when selenolates are employed, these γ-hydroxichalcogenides can be readily converted into the corresponding Morita-Baylis-Hillman adducts by oxidative elimination of the selenium moiety. In this context, herein we present a complete study on the scope and limitations of this reaction.