1415568-43-2

Basic information

• Product Name: C₁₄H₁₆⁽²⁾H₃NO₂
• CAS NO: 1415568-43-2
• Molecular Weight: 236.287
• Mol File: 1415568-43-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₆⁽²⁾H₃NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₆⁽²⁾H₃NO₂(1415568-43-2)
• EPA Substance Registry System: C₁₄H₁₆⁽²⁾H₃NO₂(1415568-43-2)

Safety Data

• Hazardous Substances Data: 1415568-43-2(Hazardous Substances Data)

Upstream product

• 917484-74-3 (1R,2R)-N-acetyl-1,2-bis(trifluoromethanesulfonamido) cyclohexane 
• 181657-56-7 (1S,2S)-2-(benzyloxy)cyclopentanamine 

Relevant articles and documents

Nanomole-scale assignment of configuration for primary amines using a kinetic resolution strategy

The absolute configurations of primary amines were assigned using a kinetic resolution strategy with Mioskowski's enantioselective 1-(R,R) and 2-(S,S) acylating agents. A simple mnemonic was developed to determine the configuration. A pseudoenantiomeric pair of reagents, 1-(R,R) and 2-(S,S)-d 3, was prepared and used to assay primary amines on a micromolar scale. The ESI-MS readout of the resulting acetamide products reproduced the selectivity factors from kinetic experiments. The method can be used on mixtures of amines and was validated with amine samples as small as 50 nmol.