1415703-84-2Relevant academic research and scientific papers
Insight into "entrainment" in SRN1 reactions of 2,2-dichloro-1,1,1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4
Tang, Xiao-Jun,Chen, Qing-Yun
, p. 1 - 5 (2015)
An interesting entrainment process in SRN1 reactions of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with thiolates were studied by experiments and DFT calculations. The radical-anion intermediate, generated from coupling of the fluorinated ra
Copper-mediated radical cross-coupling reaction of 2,2-dichloro-1,1,1- trifluoroethane (HCFC-123) with phenols or thiophenols
Tang, Xiao-Jun,Chen, Qing-Yun
supporting information, p. 6214 - 6217 (2013/02/22)
A copper-mediated cross-coupling reaction between HCFC-123 and phenols or thiophenols has been achieved. It is found that diethyl amine, which serves as both the activator and ligand of copper, plays a key role in this reaction. Two possible radical involved processes are proposed for the reaction mechanism.
