1416319-93-1

Basic information

• Product Name: [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]phenylmethanol
• CAS NO: 1416319-93-1
• Molecular Weight: 412.575
• Mol File: 1416319-93-1.mol

Chemical Properties

• CAS DataBase Reference: [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]phenylmethanol(CAS DataBase Reference)
• NIST Chemistry Reference: [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]phenylmethanol(1416319-93-1)
• EPA Substance Registry System: [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]phenylmethanol(1416319-93-1)

Safety Data

• Hazardous Substances Data: 1416319-93-1(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 173035-11-5 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene 

Relevant articles and documents

Umpolung by N-heterocyclic carbenes: Generation and reactivity of the elusive 2,2-diamino enols (breslow intermediates)

54 years later: Saturated imidazolidin-2-ylidenes react with aldehydes to smoothly produce the elusive 2,2-diamino enols A ( Breslow intermediates , first postulated in 1958) of carbene-catalyzed umpolung reactions. The 2,2-diamino enols A react with additional aldehyde in a cross-benzoin reaction. The methylated Breslow intermediates B are accessible by deprotonation of methoxymethyl azolium salts. Copyright