1416899-55-2Relevant academic research and scientific papers
Rhodium-NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: A theoretical explanation
Pubill-Ulldemolins, Cristina,Poyatos, MacArena,Bo, Carles,Fernandez, Elena
, p. 746 - 752 (2013)
In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that modify cationic Rh(i) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to favour a less energetically demanding route towards the formation of diborated products versus allyl boronate esters.
