14173-74-1

Upstream product

• 620-19-9 1-chloromethyl-3-methyl-benzene 
• 108-98-5 thiophenol 
• 108-38-3 m-xylene 
• 882-33-7 diphenyldisulfane 
• 620-13-3 1-bromomethyl-3-methyl-benzene 

Downstream Products

• 4662-96-8 1,2-di-m-tolylethane 
• 882-33-7 diphenyldisulfane 
• 180746-12-7 1-methyl-3-((phenylsulfinyl)methyl)benzene 
• 1365610-85-0 (R)-(+)-3-methylbenzyl phenyl sulfoxide 
• 139-66-2 diphenyl sulfide 
• 108-38-3 m-xylene 
• 620-23-5 m-tolyl aldehyde 

Relevant academic research and scientific papers

Eosin-Y-Catalyzed Photoredox C?S Bond Formation: Easy Access to Thioethers

An operationally simple Eosin Y catalyzed sulfenylation of hydrazones has been realized to afford a range of thioethers under visible light. The methodology provides high yields of thioethers under ambient conditions employing readily available and inexpensive starting materials. The reaction has broad substrate scope and is compatible with various functional groups.

A comparative study of Cu(II)-assisted vs Cu(II)-free chalcogenation on benzyl and 2°/3°-cycloalkyl moieties

A relative synthetic strategy toward intermolecular oxidative C -Chalcogen bond formation of alkanes has been illustrated using both Cu(II) assisted vs Cu(II) free conditions. This led to construction of a comparative study of hydrocarbon benzylic and 2°/ 3°-cycloalkyl moieties bond sulfenylation and selenation protocol by the chalcogen sources, particularly sulfur and selenium, respectively. In addition, this protocol disclosed the auspicious formation of sp3 C-S coupling products over leading the sp3 C-N coupling products by using 2-mercaptobenzothiazole (MBT) substrates.

Zn in ionic liquid: An efficient reaction media for the synthesis of diorganyl chalcogenides and chalcogenoesters

A straightforward and efficient methodology is described to synthesize structurally diverse diorganyl selenides, sulfides, seleno- and thioesters by using commercially available Zn dust in ionic liquid. Excellent yields were achieved under neutral conditions at room temperature in a short time. The solvent/ionic liquid is reusable and exhibited higher performance as compared with organic solvents.

Bimetallic system for the synthesis of diorganyl selenides and sulfides, chiral β-seleno amines, and seleno- and thioesters

The bimetallic reagent Sn(II)/Cu(II) in [bmim]BF4 was efficiently used for the cleavage of diaryl diselenides and disulfides and reacts with a variety of organic substrates, such as organic halides, acid chlorides, and β-amino mesylates affording the diorganyl selenides and sulfides within very short reaction times, under mild conditions and with excellent yields, using BMIM-BF4 as a reusable solvent.

The regioselectivity of addition of organolithium reagents to enones and enals: The role of HMPA

The role of polar solvents (particularly HMPA) in controlling the ratio of 1.2 to 1,4 addition of sulfur-substituted organolithium reagents to cyclohexenones and hexenal was studied. Low-temperature, multinuclear NMR studies provided quantitative informat