1417902-11-4

Basic information

• Product Name: 4-(((tert-butyl)dimethylsilyl)oxy)-5-(4-nitrophenyl)-2-(thiophen-2-yl)thiazole
• Synonyms: 4-(((tert-butyl)dimethylsilyl)oxy)-5-(4-nitrophenyl)-2-(thiophen-2-yl)thiazole
• CAS NO: 1417902-11-4
• Molecular Weight: 418.613
• Mol File: 1417902-11-4.mol

Chemical Properties

• CAS DataBase Reference: 4-(((tert-butyl)dimethylsilyl)oxy)-5-(4-nitrophenyl)-2-(thiophen-2-yl)thiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(((tert-butyl)dimethylsilyl)oxy)-5-(4-nitrophenyl)-2-(thiophen-2-yl)thiazole(1417902-11-4)
• EPA Substance Registry System: 4-(((tert-butyl)dimethylsilyl)oxy)-5-(4-nitrophenyl)-2-(thiophen-2-yl)thiazole(1417902-11-4)

Safety Data

• Hazardous Substances Data: 1417902-11-4(Hazardous Substances Data)

Upstream product

• 1376711-44-2 5-(4-nitrophenyl)-2-(thiophen-2-yl)thiazol-4-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 1417902-15-8 4-(4-(((tert-butyl)dimethylsilyl)oxy)-2-(thiophen-2-yl)thiazol-5-yl)aniline 
• 1417902-27-2 2-(thiophen-2-yl)-5-(4-(2,4,6-triphenylpyridin-1-ium-1-yl)phenyl)thiazol-4-olate 

Relevant articles and documents

Synthesis, properties and quantum chemical evaluation of solvatochromic pyridinium-phenyl-1,3-thiazol-4-olate betaine dyes

The syntheses and characterizations of four zwitterionic betaines are presented. These dyes possess an uncommon heterocyclic 1,3-thiazol-4-olate donor moiety. The natures of the HOMO/LUMO transitions and of the intramolecular charge-transfer state were assigned with the help of quantum chemical calculations. Multiple intermolecular solute/solvent interactions were discussed using linear solvation energy relationship (LSER) with Kamlet-Taft and Catalán parameters. The dyes show a pronounced negative solvatochromism ranging from λmax 392 nm in TFE to 820 nm in THF (Δλ=428 nm or 1.65 eV). The X-ray structures of one of the tetrafluoroborate salts and of one of the betaines are discussed.