141810-64-2

Upstream product

• 40653-32-5 methyl 2,3,4-tri-O-benzyl-β-D-galactopyranoside 
• 141810-62-0 phenyl 3-O-benzyl-4,6-O-benzylidene-2-O-phenoxythiocarbonyl-1-thio-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 128848-51-1 phenyl 3-O-benzyl-4,6-O-benzylidene-1-deoxy-1-thio-β-D-glucopyranoside 
• 71676-30-7 (2R,4aR,6S,7R,8R,8aS)-2-Phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Relevant academic research and scientific papers

A stereospecific approach towards the synthesis of 2-deoxy α- and β-glycosides based on a 1,2-ethyl (phenyl) thio group migration

Iodonium ion (NIS/TfOH)-assisted glycosylation of a sugar acceptor with properly protected ethyl (phenyl) 2-O-phenoxythiocarbonyl 1-thio-β-D-gluco- or 1-thio-α-D-mannopyranoside donors gives the respective 1,2-trans linked 2'-ethyl (phenyl) thio-2'-deoxy-α-D-manno- or β-D-glucopyranosides.

Stereospecific 1,2-ethyl(phenyl)thio group migration in sugars: Stereocontrolled synthesis of precursors to α- and β-2-deoxyglycosides

lodonium ion (NIS/TfOH, cat.) assisted glycosylation of a sugar acceptor with properly protected enthyl(phenyl)-2-O-phenoxythiocarbonyl 1-thio-β-D-gluco- or 1-thio-α-D-mannopyranoside donors gives the respective 1,2-trans linked 2′-ethyl(phenyl