141810-68-6

Basic information

• Product Name: methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-benzyl-2-deoxy-2-phenylthio-β-D-glucopyranosyl)-β-D-galactopyranoside
• Synonyms: methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-benzyl-2-deoxy-2-phenylthio-β-D-glucopyranosyl)-β-D-galactopyranoside
• CAS NO: 141810-68-6
• Molecular Weight: 989.239
• Mol File: 141810-68-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-benzyl-2-deoxy-2-phenylthio-β-D-glucopyranosyl)-β-D-galactopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-benzyl-2-deoxy-2-phenylthio-β-D-glucopyranosyl)-β-D-galactopyranoside(141810-68-6)
• EPA Substance Registry System: methyl 2,3,4-tri-O-benzyl-6-O-(3,4,6-tri-O-benzyl-2-deoxy-2-phenylthio-β-D-glucopyranosyl)-β-D-galactopyranoside(141810-68-6)

Safety Data

• Hazardous Substances Data: 141810-68-6(Hazardous Substances Data)

Upstream product

• 127299-77-8 phenyl 3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 138181-67-6 phenyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 40653-32-5 methyl 2,3,4-tri-O-benzyl-β-D-galactopyranoside 
• 141810-66-4 phenyl 3,4,6-tri-O-benzyl-2-O-phenoxythiocarbonyl-1-thio-α-D-mannopyranoside 

Downstream Products

• 117841-70-0 (2R,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-((2R,4R,5S,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxymethyl)-6-methoxy-tetrahydro-pyran 

Relevant articles and documents

A stereospecific approach towards the synthesis of 2-deoxy α- and β-glycosides based on a 1,2-ethyl (phenyl) thio group migration

Iodonium ion (NIS/TfOH)-assisted glycosylation of a sugar acceptor with properly protected ethyl (phenyl) 2-O-phenoxythiocarbonyl 1-thio-β-D-gluco- or 1-thio-α-D-mannopyranoside donors gives the respective 1,2-trans linked 2'-ethyl (phenyl) thio-2'-deoxy-α-D-manno- or β-D-glucopyranosides.