14184-22-6Relevant articles and documents
Structure, Harmonic Force Field and Hyperfine Coupling Constants of Nitrosyl Chloride
Gotehouse, Bethany,Meuller, Holger S. P.,Heineking, Nils,Gerry, Michael C. L.
, p. 3347 - 3356 (1995)
The pure rotational spectra of five isotropic species of nitrosyl chloride were measured using a cavity pulsed microwave Fourier-transform spectometer.Some a-type transitions of all five isotopomers, and some weak b-type transitions of four of these isotopomers were measured in the 4-26 GHz frequency range.Precise values for the rotational constants and the quartic centrifugal distortion constants were obtained.The rotational constants were used in structure determinations and the centrifugal distortion constants were used in a refinement of the harmonic general valence force field.A harmonic central valence force field was also calculated.Hyperfine structure in these transitions arising from quadrupole and spin-rotation coupling interactions was also observed.Diagonal and off-diagonal quadrupole coupling constants and diagonal spin-rotation coupling constants of both the chlorine and nitrogen nuclei were determined.The principal quadrupole coupling constants were evaluated and used to calculate the approximate ionic character of the N-Cl bond.The spin-rotational coupling constants were used to calculate the diamagnetic shielding factor for the nitrogen nucleus; the magnitude of this value indicates a fairly ionic N-Cl bond.
Six-coordinate nitrosyl and nitro complexes of meso - Tetratolylporphyrinatocobalt with trans sulfur-donor ligands
Kurtikyan, Tigran S.,Gulyan, Gurgen M.,Dalaloyan, Arina M.,Kidd, Bryce E.,Goodwin, John A.
, p. 7793 - 7798 (2010/12/20)
By Fourier transform infrared and optical spectroscopy, it has been observed that interactions of dimethyl sulfide and tetrahydrothiophene with nitrosyl and nitro complexes of meso-tetra-p-tolylporphyrinatocobalt [Co(TTP)] lead to the formation of previou
Reactions of nitrogen oxides with heme models: Spectral characterization of an elusive five-coordinate FeIII(porphyrin) nitrito intermediate
Kurtikyan, Tigran S.,Ford, Peter C.
, p. 492 - 496 (2007/10/03)
(Chemical Equation Presented) The famous five: The elusive five-coordinate nitrito complexes [FeIII(por)(ONO)] (por = meso- tetraphenylporphyrinato dianion or meso-tetra-p-tolylporphyrinato dianion) have been obtained by interaction of low-pres