1418581-63-1Relevant academic research and scientific papers
Activation of a 1-chlorophosphirane complex by aluminum trichloride: Generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
Ho, Feny,Ganguly, Rakesh,Mathey, Fran?ois
, p. 4726 - 4729 (2014)
Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The W(CO)5 complex of the 1-ferrocenylphosphirane is an efficient precursor of the phosphinidene complex [FcP-W(CO)5], which is trapped by tolan, trans-stilbene, and water.
Facile phosphorus-carbon bond formation using a tungsten-coordinated phosphirenyl cation
Jayaraman, Arumugam,Sterenberg, Brian T.
, p. 745 - 747 (2013/03/14)
Reaction of K2[W(CO)5] with Cl2PN-i- Pr2 in the presence of diphenylacetylene leads to the tungsten aminophosphirene complex [W(CO)5{P(N-i-Pr2)C(Ph)C(Ph)}] (1), which can be converted to th
