141885-90-7Relevant academic research and scientific papers
Chemoenzymatic synthesis of the C10-C23 segment of dictyostatin
Prusov, Evgeny,Roehm, Hartmut,Maier, Martin E.
, p. 1025 - 1028 (2007/10/03)
Employing enzymatic desymmetrization and resolution, respectively, the two aldehydes 8 and 20 were prepared. The precursor to aldehyde 8, meso-2,4-dimethylglutaric anhydride 3, could be obtained by base treatment of the diastereomeric mixture. Aldehyde 8
Enantioselective transesterification of 2-methyl-1,3-propanediol derivatives catalyzed by Pseudomonas fluorescens lipase in an organic solvent
Grisenti,Ferraboschi,Manzocchi,Santaniello
, p. 3827 - 3834 (2007/10/02)
The irreversible transesterification of racemic 2-methyl-1,3-propanediol derivatives, the monoethers 3a, 3b, 5a, and the monobenzoate 5b, with vinyl acetate catalyzed by Pseudomonas fluorescens lipase in chloroform affords enantiomerically pure chiral synthons.
