141964-64-9Relevant academic research and scientific papers
An electrophilic reagent for the synthesis of OCHFMe-containing molecules
Carbonnel, Elodie,Pannecoucke, Xavier,Besset, Tatiana,Jubault, Philippe,Poisson, Thomas
, p. 2491 - 2493 (2018/03/21)
Herein the synthesis of a novel and bench stable electrophilic reagent to construct the OCFHMe motif from O-nucleophiles has been described. This sulfonium salt, readily obtained in 5 steps, reacted with various phenols and alcohols. The resulting products, including complex molecules, were obtained in good yields. This reagent was also used for the functionalization of thiol derivatives.
THE SYNTHESIS OF (1-FLUOROVINYL)TRIBUTYLTIN: A SYNTHETIC EQUIVALENT FOR THE 1-FLUOROETHENE ANION.
Matthews, Donald P.,Waid, Philip P.,Sabol, Jeffrey S.,McCarthy, James R.
, p. 5177 - 5180 (2007/10/02)
The synthesis of (1-fluorovinyl)tributyltin (1b) is reported, and the utility of 1b as a synthetic equivalent for the 1-fluoroethene anion 2 through palladium-catalyzed couplings is demonstrated.
