142003-66-5

Upstream product

• 142003-65-4 (1R^*,3S^*,4S^*,7S^*,8S^*)-2-benzoyl-3-(1-propyl)-5,5-dimethoxy-7,8-bis(phenylsulfonyl)-2-azabicyclo<2.2.2>octane 
• 620-08-6 4-methoxypyridine 
• 142038-13-9 (1R^*,3S^*,4S^*,7S^*,8S^*)-2-benzoyl-3-(1-propyl)-5-methoxy-7,8-bis(phenylsulfonyl)-2-azabicyclo<2.2.2>oct-5-ene 
• 142003-71-2 (4-Methoxy-2-propyl-2H-pyridin-1-yl)-phenyl-methanone 
• 98-88-4 benzoyl chloride 

Downstream Products

• 142003-67-6 (1R^*,3S^*,4S^*)-2-benzyl-3-(1-propyl)-8,8-dimethoxy-2-azabicyclo<2.2.2>oct-5-ene 
• 142003-68-7 (1R^*,3S^*,4S^*)-2-benzyl-3-(1-propyl)-2-azabicyclo<2.2.2>oct-7-en-5-one 
• 142003-69-8 (1R^*,3S^*,4S^*,5S^*)-2-benzyl-3-(1-propyl)-5-<(E)-2-(dimethylphenylsilyl)-1-ethenyl>-2-azabicyclo<2.2.2>oct-7-en-5-ol 

Relevant academic research and scientific papers

Stereospecific Total Syntheses of Decahydroquinoline Alkaloids (+/-)-195A and (+/-)-2-epi-195A

The total syntheses of decahydroquinoline alkaloids (+/-)-195A (pumiliotoxin C) and (+/-)-2-epi-195A are described.An unexpected, stereospecific epimerization of the C2 stereocenter of intermediate 6a occurred during its reduction.The isomerization result