142029-07-0

Basic information

• Product Name: {Re(N₂){SC₆H₂(CH(CH₃)2)2Br}3P(C₆H₅)3}
• CAS NO: 142029-07-0
• Molecular Weight: 1293.2
• Mol File: 142029-07-0.mol

Chemical Properties

• CAS DataBase Reference: {Re(N₂){SC₆H₂(CH(CH₃)2)2Br}3P(C₆H₅)3}(CAS DataBase Reference)
• NIST Chemistry Reference: {Re(N₂){SC₆H₂(CH(CH₃)2)2Br}3P(C₆H₅)3}(142029-07-0)
• EPA Substance Registry System: {Re(N₂){SC₆H₂(CH(CH₃)2)2Br}3P(C₆H₅)3}(142029-07-0)

Safety Data

• Hazardous Substances Data: 142029-07-0(Hazardous Substances Data)

Upstream product

• 12103-40-1 bis(triphenylphosphine)-rhenium heptahydride 
• 99044-75-4 4-bromo-2,6-diisopropylbenzenethiol 
• 12104-75-5 pentahydridotris(triphenylphosphane)Re(V) 

Relevant articles and documents

Syntheses and Structures of , , (L = N2 or CO) and

The hydride reacted with 2,6-dimethylbenzenethiol in toluene to give a complex of stoichiometry 1.A crystal structure showed a trigonal-bipyramidal geometry about the Re with an agostic interaction to a thiolate methyl occupying an apical site, trans to the PPh3 ligand.Complex 1 reacts rapidly with MeCN to give the known 2 and with t-BuNC to form 3.The crystal structure of 3 showed trigonal-pyramidal geometry about the Re with asymmetric co-ordination of the isocyanide ligands and an unusual configuration for the thiolate aromatic groups.The reactions of the hydrides and with 2,4,6-triisopropyl-, 2,6-dimethoxy-benzenethiol and tris(2-sulfanylphenyl)phosphine were also studied.With HSC6H2(i-Pr)3-2,4,6 the dinitrogen complex 4 was formed and its structure determined.The preparations and structures of the complexes , 3(PPh3)> and (PPh3)> are also discussed.An alternative convenient route to (+) from is presented.

A d4-Thiolato-Dinitrogen Complex. The Synthesis and Crystal Structure of

or reacted with L in toluene, under dinitrogen, to give and , respectively in good yield, and under similar