12104-75-5

Upstream product

• 16940-66-2 sodium tetrahydroborate 
• 603-35-0 triphenylphosphine 
• 12103-40-1 bis(triphenylphosphine)-rhenium heptahydride 
• 108101-07-1 (η4-C5H6)Re(PPh3)2H3 
• 16853-85-3 lithium aluminium tetrahydride 
• 12104-75-5 C₅₄H₅₀P₃Re, light brown 

Downstream Products

• 108101-07-1 (η4-C5H6)Re(PPh3)2H3 
• 144564-89-6 (C₅H₅)2Y(C₄H₈O)H₄Re(P(C₆H₅)3)3 
• 142029-05-8 {Re(N₂){SC₆H₂(CH(CH₃)2)3}3P(C₆H₅)3} 
• 170472-51-2 [ReH₄(PPh₃)4][ReO(SC₆H₂Pr(i)3-2,4,6)4] 
• 142029-07-0 {Re(N₂){SC₆H₂(CH(CH₃)2)2Br}3P(C₆H₅)3} 
• 108571-96-6 [ReH₄(PPh₃)₃(NCMe)]PF₆ 
• 108547-90-6 ReH₄(P(C₆H₅)3)4⁽¹⁺⁾*PF₆^(1-)={ReH₄(P(C₆H₅)3)4}PF₆ 
• 108530-79-6 ReH₄(P(C₆H₅)3)3(CNC₆H₃(CH₃)2)⁽¹⁺⁾*PF₆^(1-)={ReH₄(P(C₆H₅)3)3(CNC₆H₃(CH₃)2)}PF₆ 
• 108530-77-4 ReH₃(P(C₆H₅)3)3(NCCH₃) 
• 80006-29-7 [Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate 
• 80006-27-5 [Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate 
• 25948-68-9 ReH₄I(PPh₃)₃ 
• 122169-15-7 C₅₄H₅₀P₃Re, pale yellow 

Relevant academic research and scientific papers

Reactions of the eight-coordinate rhenium complex ReH4(hq)(PPh3)2 (hq = 2-hydroxyquinoline monoanion) with monodentate tertiary phosphines: Formation of pentagonal bipyramidal dihydridorhenium(III) complexes of the type ReH2(hq)(PPh3)2(PR3)

The reactions of ReH4(hq)(PPh3)2, where hq represents the monoanion of 2-hydroxyquinoline, with monodentate phosphines afford the seven-coordinate complexes ReH2(hq)(PPh3)2(PR3) (PR3 = PMe3 (1), PMe2Ph (2), PMePh2 (3), PPh3 (4), and PHPh2 (5)) which have been shown to possess pentagonal bipyramidal structures on the basis of X-ray crystal structure determinations of 1, 4, and 5. The unique PR3 ligand occupies the pentagonal plane in the case of 1 and 5. The reactions of 4 with PMe3 and PHPh2 lead to substitution of one of the PPh3 ligands and the formation of 1 and 5, respectively. The mild thermolysis of solutions of 4 in refluxing benzene affords the diphenyphosphine complex 5, along with some decomposition of 4 and the release of free PPh3; when this reaction is carried out in C6D6, the released PPh3 is found to contain the isotopomers PPh3-d0 through PPh3-d6 with the deuteration taking place only in the ortho positions.

Reaction of thiolato-ligands with rhenium hydrides - III. Complexes of mercaptopyridines. The syntheses and X-Ray crystal structures of [ReHF(2-SC5H4N)2(PMe2Ph) 2]BF4 and [ReH(2-SC5

The hydride complex [ReH5(PMe2Ph)3] reacted with 2-mercaptopyridine(pySH) in the presence of HBF4 giving [ReH(pyS)(PMe2Ph)4]BF4 (1) and [ReHF(pyS)2 (PMe2Ph)

Syntheses and Structures of , , (L = N2 or CO) and

The hydride reacted with 2,6-dimethylbenzenethiol in toluene to give a complex of stoichiometry 1.A crystal structure showed a trigonal-bipyramidal geometry about the Re with an agostic interaction to a thiolate methyl occupying an apical site, trans to the PPh3 ligand.Complex 1 reacts rapidly with MeCN to give the known 2 and with t-BuNC to form 3.The crystal structure of 3 showed trigonal-pyramidal geometry about the Re with asymmetric co-ordination of the isocyanide ligands and an unusual configuration for the thiolate aromatic groups.The reactions of the hydrides and with 2,4,6-triisopropyl-, 2,6-dimethoxy-benzenethiol and tris(2-sulfanylphenyl)phosphine were also studied.With HSC6H2(i-Pr)3-2,4,6 the dinitrogen complex 4 was formed and its structure determined.The preparations and structures of the complexes , 3(PPh3)> and (PPh3)> are also discussed.An alternative convenient route to (+) from is presented.