1420831-79-3

Basic information

• Product Name: [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)]
• Synonyms: [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)]
• CAS NO: 1420831-79-3
• Molecular Weight: 853.943
• Mol File: 1420831-79-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)](1420831-79-3)
• EPA Substance Registry System: [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)](1420831-79-3)

Safety Data

• Hazardous Substances Data: 1420831-79-3(Hazardous Substances Data)

Upstream product

• 1420831-81-7 [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphine)(COD)][PF₆] 
• 887605-61-0 bis[(2-diphenylphosphino)phenyl]phosphine 
• 1360594-29-1 [Ir(cod)NH₂]₂ 

Downstream Products

• 1420831-84-0 [Ir(MeP(C₆H₄PPh₂)₂)(COD)]I 
• 1420831-81-7 [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphine)(COD)][PF₆] 

Relevant articles and documents

Reactivity of a mononuclear iridium(I) species bearing a terminal phosphido fragment embedded in a triphosphorus ligand

The first example of an iridium(I) species bearing a terminal phosphido (PR2-) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium(I)-gold(I) dinuclear species.