1420831-84-0Relevant articles and documents
Reactivity of a mononuclear iridium(I) species bearing a terminal phosphido fragment embedded in a triphosphorus ligand
Gloaguen, Yann,Jacobs, Wesley,De Bruin, Bas,Lutz, Martin,Van Der Vlugt, Jarl Ivar
, p. 1682 - 1684 (2013)
The first example of an iridium(I) species bearing a terminal phosphido (PR2-) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium(I)-gold(I) dinuclear species.