14212-98-7

Basic information

• Product Name: phenyl bis(chloromethyl)phosphinate
• Synonyms: PHENYL BIS(CHLOROMETHYL) PHOSPHINATE
• CAS NO: 14212-98-7
• Molecular Formula: C₈H₉Cl₂O₂P
• Molecular Weight: 239.0356
• Mol File: 14212-98-7.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 300.6°C at 760 mmHg
• Flash Point: 174.9°C
• Density: 1.351g/cm³
• Vapor Pressure: 0.00198mmHg at 25°C
• Refractive Index: 1.524
• CAS DataBase Reference: phenyl bis(chloromethyl)phosphinate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl bis(chloromethyl)phosphinate(14212-98-7)
• EPA Substance Registry System: phenyl bis(chloromethyl)phosphinate(14212-98-7)

Safety Data

• Hazardous Substances Data: 14212-98-7(Hazardous Substances Data)

Upstream product

• 13482-64-9 bis(chloromethyl)phosphinic chloride 
• 1529-17-5 phenyltrimethylsilyl ether 
• 108-95-2 phenol 
• 622-46-8 carbamic acid phenyl ester 
• 33714-89-5 4-nitrophenyl bis(chloromethyl)phosphinate 

Downstream Products

• 87517-96-2 trans-Phenyl <2-(4-nitrophenyl)ethenyl>(chloromethyl)phosphinate 
• 87517-95-1 cis-Phenyl <2-(4-nitrophenyl)ethenyl>(chloromethyl)phosphinate 
• 80991-34-0 (S)-Phenyl (3,4-dioctadecoxybutyl)<(diethoxyphosphinyl)methyl>phosphinate 
• 87517-94-0 (R)-Phenyl (3,4-dioctadecoxybut-1-enyl)(chloromethyl)phosphinate 
• 908809-02-9 [(3,4-Bis-octadecyloxy-butyl)-phenoxy-phosphinoylmethyl]-phosphonic acid 
• 344601-18-9 Chloromethyl-[(triphenyl-λ⁵-phosphanylidene)-methyl]-phosphinic acid phenyl ester 
• 13274-83-4 di(chloromethyl)phosphinic acid 
• 108-95-2 phenol 
• 87517-93-9 Phenyl (chloromethyl)(triphenylphosphoniomethyl)phosphinate chloride 
• 16165-65-4 Bis-dimethylaminomethyl-phosphinic acid phenyl ester 
• 17052-19-6 phenyl bis(iodomethyl)phosphinate 

Relevant articles and documents

Synthesis of azaphosphacyclanes on the basis of reactions of α-aminoalkylphosphonates with bis(chloromethyl)isocyanatophosphinate

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Reactions of α-aminoalkylphosphonates with iso(thio) cyanatophosphates(phosphonates, phosphinates). Synthesis of 1,3,4- diazaphospholidines and 1,3,4-oxaza(thiaza)phospholines

Phenyl α-aminoalkylphosphonates add to phenyl iso(thio)cyanates to give saturated heterocycles, 1,3,4-diazaphospholidin-2-(thi)ones. The reaction of diphenyl (α-methylamino)benzylphosphonate with diethyl isothiocyanatophosphate involves initial formation of 1,3,4-tiazaphospholidine- 2-thiones containing exo- and endocyclic phosphorus atoms. These products are readily hydrolyzed in air, yielding diethyl isothiocyanatophosphate and phenyl hydrogen (α-methylamino)benzylphosphonate. The final products of the reaction of chloromethyl isocyanatophosphonates with aminoalkylphosphonates are 1,3,4-oxazaphospholines. Phenyl aminoalkylphosphonates react with chloromethyl isocyanatophosphonates to give saturated heterocycles, 1,3,4- diazaphospholidines, whereas with chloromethyl isothiocyanatophosphonates 1,3,4-thiazaphospholines are formed.

Reactions of chloromethylphosphonic dichlorides and bis(chloromethyl)phosphinic chlorides with trimethylethoxysilane and trimethylphenoxysilane

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