1421276-55-2Relevant articles and documents
Tosyl Hydrazine-Promoted Tandem Condensation and Cyclization of Acyl Azobenzenes Enabling Access to 2H-Indazoles under Metal-Free Aerobic Conditions
Son, Jeong-Yu,Kim, Hyunseok,Baek, Yonghyeon,Um, Kyusik,Ko, Gi Hoon,Han, Gi Uk,Han, Sang Hoon,Lee, Kooyeon,Lee, Phil Ho
, p. 4354 - 4361 (2018/10/02)
Tosyl hydrazine-promoted tandem condensation and cyclization of 2-acyl azobenzenes under metal-free aerobic conditions was demonstrated to give 2-aryl-2H-indazoles having alkyl- or aryl groups at the 3-position in quantitative yields through the release o
Rhenium-Catalyzed [4 + 1] Annulation of Azobenzenes and Aldehydes via Isolable Cyclic Rhenium(I) Complexes
Geng, Xiaoyu,Wang, Congyang
supporting information, p. 2434 - 2437 (2015/05/27)
The first Re-catalyzed [4 + 1] annulation of azobenzenes with aldehydes was developed to furnish 2H-indazoles via isolable and characterized cyclic ReI-complexes. For the first time, the acetate-acceleration effect is showcased in Re-catalyzed C-H activation reactions. Remarkably, mechanistic studies revealed an irreversible aldehyde-insertion step, which is in sharp contrast to those of previous Rh- and Co-systems. (Chemical Presented).