142176-82-7Relevant academic research and scientific papers
Stereoselective synthesis of syn1,3-diols
Mohr, Peter
, p. 2455 - 2458 (2007/10/02)
Z-allylsilanes 1 are epoxidized by V5+/TBHP with high erythro-selectivity (up to 97:3). HF- or TBAFinduced fragmentation leads to syn-l,3-diols 3. Compound 3f can be gtransformed within two steps into a key synthon for the lactone moiety of com
HIGH DIASTEREOSELECTIVITY OBSERVED IN THE VINYLATION REACTION OF α,β-EPOXY ALDEHYDES WITH β-SILYLPHOSPHOROUS YLIDE
Iio, Hideo,Mizobuchi, Tsukasa,Tokoroyama, Takashi
, p. 2379 - 2382 (2007/10/02)
The high erythro diastereofacial selectivities were observed in the silyl group migrative vinylation of α,β-epoxy aldehydes substituted by an alkyl or silyl group at the β-position using 2-diphenylmethylsilylethylidene-tris(4-methoxyphenyl)phosphorane.
