14218-12-3Relevant academic research and scientific papers
A novel and efficient method for the oxidative removal of O-benzyl protective groups of carbohydrates by tetrabutylammonium peroxydisulfate
Chen, Fen-Er,Peng, Zuo-Zhong,Fu, Han,Meng, Ge,Cheng, Yu,Lü, Yin-Xiang
, p. 627 - 628 (2007/10/03)
Various benzyl ethers of carbohydrates have been selectively oxidized to the corresponding benzoate esters 2a-j with tetrabutylammonium peroxydisulfate under neutral conditions followed by debenzoylation with sodium methoxide to afford the debenzylated carbohydrates 3a-j in good overall yields. Noteworthy is that highly chemoselective reactions were achieved with the co-existence of other functionalities. Thieme Stuttgart.
