142196-01-8

Basic information

• Product Name: {(PPh3)(η-C6H6)ReH3}
• CAS NO: 142196-01-8
• Molecular Weight: 529.635
• Mol File: 142196-01-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: {(PPh3)(η-C6H6)ReH3}(CAS DataBase Reference)
• NIST Chemistry Reference: {(PPh3)(η-C6H6)ReH3}(142196-01-8)
• EPA Substance Registry System: {(PPh3)(η-C6H6)ReH3}(142196-01-8)

Safety Data

• Hazardous Substances Data: 142196-01-8(Hazardous Substances Data)

Upstream product

• 12103-40-1 bis(triphenylphosphine)-rhenium heptahydride 
• 75359-47-6 {(PPh3)2(η-C6H6)ReH} 
• 81368-85-6 {(PPh3)2(η-C6H8)ReH3} 
• 558-37-2 tert-butylethylene 

Relevant articles and documents

Photochemical reactions of and

(Ia) reacted in tetrahydrofuran with cyclopentadiene or cyclohexa-1,4-diene under UV irradiation to give (II), and a 1:2 mixture of and (III), respectively; III was isolated from the photochemical reaction of Ia with 3,3-dimethylbutene in benzene.When using (Ib) (dppe = Ph2PCH2CH2PPh2) instead of Ia in these three reactions, no cyclopentadienyl compound was obtained, but (IV) and (V) were isolated; IV and V are precursors to arene and cyclohexadienylrhenium derivatives containing dppe.