142207-20-3Relevant academic research and scientific papers
Investigation of BF4 as a Catalyst of Hydrogen Isotope Exchange of Substrates in Solution
Heys, Richard
, p. 680 - 681 (1992)
The title complex is found to catalyse the efficient and regioselective exchange of deuterium gas with hydrogens in several substrate structural types; exchange is observed only at aromatic sites in proximity to certain nitrogen or oxygen containing funct
Cp?Co(III)-Catalyzed C-H Alkylation with Maleimides Using Weakly Coordinating Carbonyl Directing Groups
Mandal, Rajib,Emayavaramban, Balakumar,Sundararaju, Basker
, p. 2835 - 2838 (2018/05/29)
A novel protocol for ortho-C-H alkylation of aromatic and heteroaromatic ketones and esters under Cp?Co(III) catalysis has been developed for the first time. The reaction proceeds through initial cyclometalation via weak chelation-assisted C-H bond activation, followed by coordination of activated alkene, insertion between Co-C, and protodemetalation.
Application of neutral iridium(I) N-heterocyclic carbene complexes in ortho-directed hydrogen isotope exchange
Cochrane, Alison R.,Irvine, Stephanie,Kerr, William J.,Reid, Marc,Andersson, Shalini,Nilsson, Goeran N.
, p. 451 - 454 (2014/03/21)
Bench-stable complexes of the type [Ir(COD)(NHC)Cl] (NHC = N-heterocyclic carbene) have been investigated within the field of hydrogen isotope exchange. By employing a sterically encumbered NHC within such complexes and catalyst loadings of only 5 mol%, m
