1422177-77-2

Basic information

• Product Name: 2-(1,1-diphenylbut-3-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: 2-(1,1-diphenylbut-3-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 1422177-77-2
• Molecular Weight: 334.266
• Mol File: 1422177-77-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(1,1-diphenylbut-3-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1,1-diphenylbut-3-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1422177-77-2)
• EPA Substance Registry System: 2-(1,1-diphenylbut-3-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(1422177-77-2)

Safety Data

• Hazardous Substances Data: 1422177-77-2(Hazardous Substances Data)

Upstream product

• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 165904-17-6 (E)-trimethyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane 
• 91-01-0 1,1-Diphenylmethanol 

Downstream Products

• 93010-27-6 but-2-ene-1,1-diyldibenzene 
• 111171-96-1 but-2-ene-1,1-diyldibenzene 

Relevant articles and documents

Tandem reactions involving 1-silyl-3-boryl-2-alkenes. New access to (Z)-1-fluoro-1-alkenes, allyl fluorides, and diversely α-substituted allylboronates

The reactions of 1-silyl-3-boryl-2-alkenes with various electrophilic reagents (Selectfluor, N-halosuccinimides, benzhydryl, and propargylic alcohols in the presence of a Lewis acid, N-alkoxycarbonyliminium ion) have been investigated as new routes to α-substituted allylboronates. Further functional transformations, including allylboration, Suzuki coupling, protodeboronation, and cycloisomerization, have been carried out to illustrate the synthetic potential of these γ-borylallylsilanes.