111171-96-1Relevant articles and documents
Cationic and neutral diphenyldiazomethanerhodium(I) complexes as catalytically active species in the C-C coupling reaction of olefins and diphenyldiazomethane
Werner, Helmut,Schneider, Michael E.,Bosch, Marco,Wolf, Justin,Teuben, Jan H.,Meetsma, Auke,Troyanov, Sergei I.
, p. 3052 - 3059 (2000)
Cationic rhodium(I) complexes cis-[Rh(acetone)2(L)(L')]+ (2: L=L'=C8H14; 3: L=C8H14; L'=PiPr3; 4: L= L'=PiPr3), prepared from [{RhCl-(C8H14)
Tandem reactions involving 1-silyl-3-boryl-2-alkenes. New access to (Z)-1-fluoro-1-alkenes, allyl fluorides, and diversely α-substituted allylboronates
MacE, Aurelie,Tripoteau, Fabien,Zhao, Qian,Gayon, Eric,Vrancken, Emmanuel,Campagne, Jean-Marc,Carboni, Bertrand
supporting information, p. 906 - 909 (2013/03/28)
The reactions of 1-silyl-3-boryl-2-alkenes with various electrophilic reagents (Selectfluor, N-halosuccinimides, benzhydryl, and propargylic alcohols in the presence of a Lewis acid, N-alkoxycarbonyliminium ion) have been investigated as new routes to α-substituted allylboronates. Further functional transformations, including allylboration, Suzuki coupling, protodeboronation, and cycloisomerization, have been carried out to illustrate the synthetic potential of these γ-borylallylsilanes.
Palladium catalyzed isomerization of alkenes: A pronounced influence of an o-phenol hydroxyl group
Fan, Jinmin,Wan, Changfeng,Wang, Qiang,Gao, Linfeng,Zheng, Xiaoqi,Wang, Zhiyong
supporting information; experimental part, p. 3168 - 3172 (2011/02/25)
A novel palladium catalyzed isomerization of alkenes has been found, where an ortho-phenol hydroxyl group has a pronounced influence on the isomerization.