142231-18-3Relevant academic research and scientific papers
One-pot synthesis of isoxazoles from enaminones: An application of Fe(II) as the catalyst for ring expansion of 2H-azirine intermediates
Zheng, Yunhui,Yang, Chao,Zhang-Negrerie, Daisy,Du, Yunfei,Zhao, Kang
, p. 6157 - 6160 (2013/10/22)
We report an application of FeCl2 as an inexpensive, nontoxic, and efficient catalyst in a clean ring expansion reaction of 2H-azirine derivatives, an intermediate formed through the PhI(OAc)2-mediated azirination of readily availabl
The Reaction of Carbanions from 3-Methyl-5-phenylisoxazole with Electrophilic Compounds
Alberola, Angel,Calvo, Luis,Rodriguez, Teresa Rodriguez,Sanudo, Carmen
, p. 445 - 450 (2007/10/02)
The reactivity of 3-methyl-5-phenylisoxazole against electrophilic compounds in the presence of different bases is studied.With n-BuLi, alkylated products at C-4 position and C-3 methyl group, and, in a few cases, dialkylated isoxazoles are obtained.When
