1422376-20-2

Upstream product

• 55174-91-9 (-)-1,2-O-isopropylidene-5-O-pivaloyl-α-D-xylofuranose 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 1422376-15-5 1,2-O-isopropylidene-3-amino-3-deoxy-5-O-n-propyl-α-D-ribofuranoside 
• 532-20-7 D-xylofuranose 
• 14125-95-2 3-amino-3-deoxy-1,2-O-isopropylidene-α-D-ribofuranose 
• 55174-95-3 1,2-O-isopropylidene-5-O-trimethylacetyl-α-D-erythro-pent-3-ulofuranose oxime 
• 55174-92-0 1,2-O-isopropylidene-5-O-2,2-dimethylpropanoyl-α-D-erythro-pent-3-ulofuranose 

Relevant academic research and scientific papers

Sugar-based monodentate phosphoramidite ligands for Cu-catalyzed enantioselective conjugate addition to enones

In this paper we present new, monodentate phosphoramidite ligands based on amines derived from the easy available monosaccharide d-xylose and BINOLs. Ligands were used for copper-catalyzed conjugate addition to acyclic and cyclic enones. The highest enantioselectivity achieved in this study was 77% ee for the conjugate addition to trans-chalcone, which is comparable to the best results published to date for phosphoramidite ligands based on carbohydrate-derived amines.