142288-16-2

Upstream product

• 155975-26-1 (R)-2-[(S)-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-3-oxo-pyrrolidine-1-carboxylic acid ethyl ester 
• 142394-38-5 (S)-2-[(S)-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-3-oxo-pyrrolidine-1-carboxylic acid ethyl ester 
• 3751-82-4 ethyl 1-ethoxycarbonyl-4-oxopyrrolidine-3-carboxylate 
• 142288-15-1 (2R,3S)-2-[(S)-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-3-hydroxy-pyrrolidine-1-carboxylic acid ethyl ester 
• 77-76-9 2,2-dimethoxy-propane 
• 142288-15-1 (2S,3R)-2-[(S)-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-3-hydroxy-pyrrolidine-1-carboxylic acid ethyl ester 
• 81028-12-8 (4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde 

Downstream Products

• 142301-04-0 (4S,4aR,7aS)-4-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-hexahydro-[1,3]dioxino[5,4-b]pyrrole 
• 142301-04-0 (4S,4aS,7aR)-4-((4S,5S)-5-Benzyloxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-hexahydro-[1,3]dioxino[5,4-b]pyrrole 

Relevant academic research and scientific papers

N-Substituted Pyrrolidin-3-ones as Heterocyclic Building Blocks. Enantioselective Synthesis of 8-Epi- and 1,8,8a-Triepi-castanospermine

Regioselective aldol reaction of dianion 1 with aldehyde 5 provides the basis of a new approach to the construction of polyhydroxy indolizidines and the application of this methodology to the synthesis of 8-epicastanospermine 11 and 1,8,8a-triepicastanosp