1423075-93-7Relevant academic research and scientific papers
Gold-catalysed cascade rearrangements of ynamide propargyl esters
Heffernan, Stephen J.,Beddoes, James M.,Mahon, Mary F.,Hennessy, Alan J.,Carbery, David R.
, p. 2314 - 2316 (2013)
The Au(i)-catalysed rearrangement of propargylic esters formed from an ynamide has been studied. The reaction is facile, and when conducted in the presence of a reactive indole nucleophile, leads to a cascade process whereby γ-indolyl α-acyloxyenamides are formed in good yield and excellent E-stereoselectivity. The Royal Society of Chemistry.
