1423076-68-9

Upstream product

• 43157-73-9 dicarbonyl(pentamethylcyclopentadienyl)phenyliron 

Downstream Products

• 1423076-69-0 (η⁵-pentamethylcyclopentadienyl)Fe(CO)(PPh₃)(2-furyl) 
• 1423076-70-3 (η⁵-pentamethylcyclopentadienyl)Fe(CO)(PPh₃)(2-thienyl) 
• 1423076-72-5 (η⁵-pentamethylcyclopentadienyl)Fe(CO)(PPh₃)(5-methyl-2-furyl) 
• 43157-73-9 dicarbonyl(pentamethylcyclopentadienyl)phenyliron 
• 1423076-73-6 (η⁵-pentamethylcyclopentadienyl)Fe(CO)(acetonitrile)(Ph-d₅) 
• 76089-59-3 1,2,3,4-tetramethylfulvene 
• 71-43-2 benzene 
• 65-85-0 benzoic acid 

Relevant academic research and scientific papers

Facile and regioselective C-H bond activation of aromatic substrates by an fe(II) complex involving a spin-forbidden pathway

The Fe(II) complex Cp*Fe(CO)(NCMe)Ph (Cp* = η5-pentamethylcyclopentadienyl) is shown to mediate facile and highly regioselective C-H activation of aromatic substrates including benzene, furan, thiophene, thiazole, and 2-methylfuran. Experimental and computational evidence suggest a mechanism for C-H activation that involves NCMe dissociation, multiple spin intersystem crossings, C-H bond coordination, and C-H bond cleavage by a σ-bond metathesis reaction.