142370-33-0

Basic information

• Product Name: CuCl(C₅H₄NOS)(C₆H₅)2PCH₂P(C₆H₅)2
• CAS NO: 142370-33-0
• Molecular Weight: 609.555
• Mol File: 142370-33-0.mol

Chemical Properties

• CAS DataBase Reference: CuCl(C₅H₄NOS)(C₆H₅)2PCH₂P(C₆H₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: CuCl(C₅H₄NOS)(C₆H₅)2PCH₂P(C₆H₅)2(142370-33-0)
• EPA Substance Registry System: CuCl(C₅H₄NOS)(C₆H₅)2PCH₂P(C₆H₅)2(142370-33-0)

Safety Data

• Hazardous Substances Data: 142370-33-0(Hazardous Substances Data)

Upstream product

• 1121-30-8 1-hydroxy-2(1H)-pyridinethione 
• 142370-30-7 CuCl(C₅H₄NOS) 
• 2071-20-7 bis-diphenylphosphinomethane 

Relevant articles and documents

Chemistry of Mercaptopyridines and Related Ligands. Part 3. Novel Examples of Copper(II)-Tertiary Phosphine Complexes stabilized by 1-Hydroxypyridine-2-thione

reaction of 1-hydroxypyridine-2-thione (C5H5NOS) with copper(II) chloride dihydrate gave an insoluble dirty yellow compound of stoichiometry, 1 which is ESR active.Similar reaction with copper(II) bromide gave the ESR-active green compound 7.Reactions of 1 and 7 with tertiary phosphines gave mixed-ligand complexes of stoichiometry CuX(C5H4NOS)Ln , all of which are ESR active.The latter complexes represent the first novel examples of air- and moisture-stable copper(II)-tertiary phopshine complexes in which Cu(II) is bonded to one halogen, one oxygen, one sulfur and two phosphorus atoms.