Chemistry of Mercaptopyridines and Related Ligands. Part 3. Novel Examples of Copper(II)-Tertiary Phosphine Complexes stabilized by 1-Hydroxypyridine-2-thione

DOI: 10.1039/DT9920001407

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1407 - 1410 (1992)

Update date:2022-08-02

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Authors:

Lobana, Tarlok S.

Bhatia, Paramjit K.

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Article abstract of DOI:10.1039/DT9920001407

reaction of 1-hydroxypyridine-2-thione (C5H5NOS) with copper(II) chloride dihydrate gave an insoluble dirty yellow compound of stoichiometry, 1 which is ESR active.Similar reaction with copper(II) bromide gave the ESR-active green compound 7.Reactions of 1 and 7 with tertiary phosphines gave mixed-ligand complexes of stoichiometry CuX(C5H4NOS)Ln , all of which are ESR active.The latter complexes represent the first novel examples of air- and moisture-stable copper(II)-tertiary phopshine complexes in which Cu(II) is bonded to one halogen, one oxygen, one sulfur and two phosphorus atoms.

Full text of DOI:10.1039/DT9920001407

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