142467-29-6

Upstream product

• 99942-86-6 3-ethylcyclohex-2-enyl acetate 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 142467-27-4 (±)-3-ethylcyclohex-2-en-1-ol 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 17299-34-2 3-ethylcyclohex-2-en-1-one 
• 142467-28-5 ethyl (1-ethyl-2-cyclohexen-1-yl)acetate 

Downstream Products

• 103580-93-4 2-(1-ethyl-2-cyclohexen-1-yl)acetyl chloride 
• 912959-46-7 (+/-)-1-ethyl-2-cyclohexene-1-propanol acetate 
• 844655-73-8 4-[3-(acetyloxy)propyl]-4-ethyl-2-cyclohexen-1-one 
• 844655-74-9 4-[3-(acetyloxy)propyl]-4-ethyl-2-iodo-2-cyclohexen-1-one 
• 912959-47-8 4-ethyl-4-(3-hydroxypropyl)-2-(2-nitrophenyl)-2-cyclohexen-1-one 
• 844655-78-3 4-(3-azidopropyl)-4-ethyl-2-(2-nitrophenyl)-2-cyclohexen-1-one 
• 844655-76-1 4-[3-(acetyloxy)propyl]-4-ethyl-2-(2-nitrophenyl)-2-cyclohexen-1-one 
• 912959-48-9 4-ethyl-4-(3-hydroxypropyl)-2-(2-nitrophenyl)-2-cyclohexen-1-one methanesulfonate 
• 103557-92-2 benzyl N-<(3aα,12α,12aα,12bα)-1,2,3,3a,4,5,11,12,12a,12b-decahydro-3aα-ethyl-5-oxoisoquino<2,1,8-lma>carbazol-12-yl>carbamate 
• 128505-27-1 methyl (E)-3-<1-<2-(1-ethyl-2-cyclohexen-1-yl)acetyl>-1H-indol-3-yl>-2-propenoate 
• 844655-71-6 (+/-)-1-ethyl-2-cyclohexene-1-propanol 
• 844655-69-2 (+/-)-3-ethyl-3-(3-methoxy-2-propenyl)-1-cyclohexene 
• 912959-56-9 (+/-)-1-ethyl-2-cyclohexene-1-propanal 
• 912959-28-5 (+/-)-1-ethyl-2-cyclohexene-1-acetaldehyde 

Relevant academic research and scientific papers

Application of the palladium(0)-catalyzed ullmann cross-coupling reaction in a total synthesis of (±)-aspidospermidine and thus representing an approach to the lower hemisphere of the binary indole-indoline alkaloid vinblastine

As part of ongoing studies directed towards the construction of the anti-cancer agent vinblastine (1), the related but structurally less complex natural product aspidospermidine (3) has been synthesized. Two approaches to target 3 were pursued. In the fir

Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: Application to a total synthesis of the alkaloid (±)-aspidospermidine

The application of Ullmann cross-coupling reaction for the synthesis of the alkaloid (±)-aspidospermidine was studied. The initial step associated with the second stage of the synthesis of aspidospermidine involved the Pd[0]-catalyzed Ullmann cross-coupli

SYNTHESIS OF FUSED AMINOTETRAHYDROCARBAZOLE COMPOUNDS

Intramolecular Diels-Alder reaction of 3-(1H-indol-3-yl)-2-propenoates having olefinic substituents at the 1-position of the indole ring gave stereoselectively pentacyclic fused indole compounds in good yield.Aminotetrahydrocarbazoles derivatives (8, 21,