142468-72-2Relevant academic research and scientific papers
Allylic substitution of 3′,4′-unsaturated nucleosides: Organosilicon-based stereoselective access to 4′-C-branched 2′,3′-didehydro-2′,3′-dideoxyribonucleosides
Haraguchi, Kazuhiro,Tanaka, Hiromichi,Itoh, Yoshiharu,Yamaguchi, Kentaro,Miyasaka, Tadashi
, p. 851 - 858 (2007/10/03)
Reactions of organosilicon reagents (such as allyltrimethylsilane, silyl enol ethers, cyanotrimethylsilane) with 3′,4′-unsaturated nucleosides (of uracil, N4-acetylcytosine, and hypoxanthine) having an allyl ester structure were investigated in
Stereoselective synthesis of 4′-C-branched 2,′3′-didehydro-2′-dideoxy nucleosides based on SnCl4-promoted allylic rearrangement
Haraguchi, Kazuhiro,Tanaka, Hiromichi,Itoh, Yoshiharu,Saito, Shigeru,Miyasaka, Tadashi
, p. 2841 - 2844 (2007/10/02)
Based on SnCl4-[promoted allylic rearrangement between a 3′,4′-unsaturated uracil nucleoside and organosilicon reagents, stereoselective introduction of carbon functionalities to the 4′-position has been accomplished, disclosing a new entry for
