1424934-11-1

Basic information

• Product Name: C₁₅H₁₇FOSi
• CAS NO: 1424934-11-1
• Molecular Weight: 260.383
• Mol File: 1424934-11-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₅H₁₇FOSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₁₇FOSi(1424934-11-1)
• EPA Substance Registry System: C₁₅H₁₇FOSi(1424934-11-1)

Safety Data

• Hazardous Substances Data: 1424934-11-1(Hazardous Substances Data)

Upstream product

• 459-57-4 4-fluorobenzaldehyde 
• 768-33-2 phenyldimethylsilyl chloride 
• 3839-31-4 dimethyl(phenyl)silyllithium 

Downstream Products

• 1504663-20-0 [dimethylphenylsilyl(4-fluorophenyl)methoxy]trimethylsilane 
• 32222-45-0 4-fluoromandelic acid 
• 127709-19-7 methyl 4-fluoro-α-hydroxyphenylacetate 

Relevant articles and documents

Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes Initiated by Enantioselective Copper-Catalyzed Borylation

An efficient synthesis of functionalized tertiary α-silyl alcohols by an enantio- and diastereoselective copper-catalyzed three-component coupling of 1,3-dienes, bis(pinacolato)diboron, and acylsilanes is reported. The reaction proceeds well with different 1,3-dienes and a broad range of aryl- as well as alkenyl- but also alkyl-substituted acylsilanes. The target compounds are formed with high regio-, diastereo-, and enantioselectivity (up to 99 % ee and d.r. >20:1) and are highly versatile synthetic building blocks.