142502-77-0Relevant academic research and scientific papers
Synthesis of vicinal perfluoroalkyl enol ethers
Zoghlami,Chehidi,Chaabouni,Baklouti
, p. 1887 - 1892 (2007/10/03)
A convenient preparation of vicinal perfluoroalkyl enol ethers, by the action of alcohols on 1-bromo-1-perfluoroalkylethylenes in the presence of potassium hydroxide, is described. Some aspects of their reactivity are reported.
Synthesis of fluoroalkyl ethanal: R(F)CH2CHO
Laurent,Blancou,Commeyras
, p. 2489 - 2492 (2007/10/02)
Aldehydes R(F)CH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. R(F)CH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, R(F)CH2CHO and its acylal or acetal derivatives are obtained in good yields.
