1425052-44-3Relevant articles and documents
Ligand-Enabled Alkynylation of C(sp3)?H Bonds with Palladium(II) Catalysts
Fu, Haiyan,Shen, Peng-Xiang,He, Jian,Zhang, Fanglin,Li, Suhua,Wang, Peng,Liu, Tao,Yu, Jin-Quan
supporting information, p. 1873 - 1876 (2017/02/05)
The palladium(II)-catalyzed β- and γ-alkynylation of amide C(sp3)?H bonds is enabled by pyridine-based ligands. This alkynylation reaction is compatible with substrates containing α-tertiary or α-quaternary carbon centers. The β-methylene C(sp
Palladium(0)-catalyzed alkynylation of C(sp3)-H bonds
He, Jian,Wasa, Masayuki,Chan, Kelvin S. L.,Yu, Jin-Quan
supporting information, p. 3387 - 3390 (2013/04/24)
The alkynylation of β-C(sp3)-H bonds in aliphatic amides with alkynyl halides has been enabled using Pd(0)/N-heterocyclic carbene (NHC) and Pd(0)/phosphine (PR3) catalysts. This is the first example of utilizing [AlkynylPd(II)Ln