14251-63-9

Upstream product

• 766-90-5 cis-1-phenyl-1-propylene 
• 40626-59-3 (1R*,1S*)-2-bromo-1-fluoro-1-phenylpropane 
• 637-50-3 1-phenylpropene 
• 40626-59-3 (2-bromo-1-fluoropropyl)benzene 
• 61153-41-1 (1R*,1S*)-1-fluoro-2-iodo-1-phenylpropane 
• 873-66-5 1-propenylbenzene 

Downstream Products

• 1192149-47-5 (E)-α-fluoro-β-methylstyrene oxide 
• 1192149-48-6 (E)-α-fluoro-β-methylstyrene oxide 

Relevant academic research and scientific papers

SYNTHESE D'ETHYLENIQUES MONOFLUORES

Monofluorinated ethylenic compounds have been prepared by action of potassium tertiobutylate either on 2-fluorotosylates or 2-fluorochlorides.In the case of 2-fluorochlorides the action, at higher temperature, of basic salt such as KF in ethylene glycol, may be used to prepare monofluorinated ethylenics compounds.

Asymmetric epoxidation of fluoroolefins by chiral dioxirane. Fluorine effect on enantioselectivity

(Chemical Equation Presented) The asymmetric epoxidation of various fluoroolefins has been studied using chiral ketone catalyst, and up to 93% ee was achieved with fructose-derived ketone 1.

Halofluorination of alkenes with ionic liquid EMIMF(HF)2.3

Halofluorination of alkene by means of N-halosuccinimide and ionic liquid, 1-ethyl-3-methylimidazorium oligo hydrogenfluoride (EMIMF(HF)2.3), was demonstrated. Various alkenes were converted into β-halo organofluorides in good yields after non-

Asymmetric cyclopropanation of vinyl fluorides: Access to enantiopure monofluorinated cyclopropane carboxylates

The transition metal catalyzed cyclopropanation with alkyl diazoacetates of aliphatic or aromatic vinyl fluorides, prepared from the corresponding alkenes by bromofluorination and subsequent dehydrobromination, provides a smooth access to racemic I:1 mixt

Halofluorination of Alkenes Using Dilute Hydrofluoric Acid

Iodofluorination of alkenes was achieved with N-iodosuccinimide, potassium hydrogendifluoride, and 1 M hydrofluoric acid using tetrabutylammonium fluoride as a phase-transfer catalyst.The active fluorinating reagent was shown to be tetrabutylammonium dihy

Halofluorination of Alkenes Using Tetrabutylammonium Dihydrogentrifluoride

Regio-, stereo-, and chemoselective halofluorination of alkenes is achieved using N-haloamides and tetrabutylammonium dihydrogentrifluoride, and the resulting F-I adducts were successfully converted into fluoroalkenes under dehydroiodation with 1,8-diazab